For the synthesis of NbB 2, appropriate quantities of Nb 2 O 5, boron carbide and petroleum coke in the ratio as per Table 1 were mixed thoroughly using a motorized mortar and pestle (Pulverisette 2, Fritsch GmbH, Idar Oberstelin, Germany) for small volume and planetary ball (WC) mill (PBM, Insmart Systems, Hyderabad, India) for large volume in wet media (Isopropyl alcohol) for 4 h.
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